Material Safety Data Sheet 5-Chloro-2-nitrobenzotrifluoride, 99% ACC# 16725 Section 1 - Chemical Product and Company Identification MSDS Name: 5-Chloro-2-nitrobenzotrifluoride, 99% Catalog Numbers: AC109710000, AC109710050, AC109710250 Synonyms: 5-Chloro-2-nitro-alpha1,alpha1,alpha1-trifluorotoluene Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 Section 2 - Composition, Information on Ingredients CAS#Chemical NamePercentEINECS/ELINCS 118-79-62,4,6-Tribromophenol98.0 204-278-6 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear brown liquid. Caution! Harmful. The toxicological properties of this material have not been fully investigated. Target Organs: None known. Potential Health Effects Eye: May cause eye irritation. Skin: Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. The toxicological properties of this substance have not been fully investigated. Inhalation: Harmful if inhaled. The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Flash Point: 102 deg C ( 215.60 deg F) Autoignition Temperature: > 450 deg C (> 842.00 deg F) Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: Not published. Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - Handling and Storage Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits Chemical NameACGIHNIOSHOSHA - Final PELs 2,4,6-Tribromophenol none listed none listed none listed OSHA Vacated PELs: 2,4,6-Tribromophenol: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: clear brown Odor: Not available. pH: Not available. Vapor Pressure: 1.3 hPa @ 60 deg C Vapor Density: Not available. Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 222 - 224 deg C @ 760.00mm Hg Freezing/Melting Point:21 deg C Decomposition Temperature:> 300 deg C Solubility: IN WATER: 168 MG/L (20°C) Specific Gravity/Density:1.5260g/cm3 Molecular Formula:C7H3ClF3NO2 Molecular Weight:225.55 Section 10 - Stability and Reactivity Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Strong bases, strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 118-79-6: SN1225000 LD50/LC50: CAS# 118-79-6: Draize test, rabbit, eye: 100 mg Mild; Inhalation, rat: LC50 = >1630 mg/m3/4H; Oral, rat: LD50 = 200 mg/kg; . Carcinogenicity: CAS# 118-79-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information available. Teratogenicity: No information available. Reproductive Effects: No information available. Mutagenicity: No information available. Neurotoxicity: No information available. Other Studies: Section 12 - Ecological Information No information available. Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information US DOTCanada TDG Shipping Name:DOT regulated - small quantity provisions apply (see 49CFR173.4)No information available. Hazard Class: UN Number: Packing Group: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 118-79-6 is listed on the TSCA inventory. Health & Safety Reporting List CAS# 118-79-6: Effective 1/11/90, Sunset 6/30/98 Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b CAS# 118-79-6: Section 4 (see 40 CFR 707.72) TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 118-79-6: 100 lb final RQ; 45.4 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 118-79-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 118-79-6: No information available. Canada - DSL/NDSL CAS# 118-79-6 is listed on Canada's DSL List. Canada - WHMIS WHMIS: Not available. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List Section 16 - Additional Information MSDS Creation Date: 9/02/1997 Revision #4 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.